Terpinolenska sintaza
Terpinolenska sintaza (EC 4.2.3.113, ag9, PmeTPS2, LaLIMS_RR) je enzim sa sistematskim imenom geranil-difosfat difosfat-lijaza (ciklizacija, formira terpinolen).[1][2][3][4][5] Ovaj enzim katalizuje sledeću hemijsku reakciju
| Terpinolenska sintaza | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifikatori | |||||||||
| EC broj | 4.2.3.113 | ||||||||
| Baze podataka | |||||||||
| IntEnz | IntEnz pregled | ||||||||
| BRENDA | BRENDA pristup | ||||||||
| ExPASy | NiceZyme pregled | ||||||||
| KEGG | KEGG pristup | ||||||||
| MetaCyc | metabolički put | ||||||||
| PRIAM | profil | ||||||||
| Strukture PBP | RCSB PDB PDBe PDBj PDBsum | ||||||||
| |||||||||
- geranil difosfat terpinolen + difosfat
Za dejstvo ovog enzima je neophodan jon Mg2+.
Reference уреди
- ^ Croteau, R. & Satterwhite, D.M. (1989). „Biosynthesis of monoterpenes. Stereochemical implications of acyclic and monocyclic olefin formation by (+)- and (-)-pinene cyclases from sage”. J. Biol. Chem. 264: 15309—15315. PMID 2768265.
- ^ Bohlmann, J., Phillips, M., Ramachandiran, V., Katoh, S. and Croteau, R. (1999). „cDNA cloning, characterization, and functional expression of four new monoterpene synthase members of the Tpsd gene family from grand fir (Abies grandis)”. Arch. Biochem. Biophys. 368: 232—243. PMID 10441373.
- ^ Faldt, J., Martin, D., Miller, B., Rawat, S. and Bohlmann, J. (2003). „Traumatic resin defense in Norway spruce (Picea abies): methyl jasmonate-induced terpene synthase gene expression, and cDNA cloning and functional characterization of (+)-3-carene synthase”. Plant Mol. Biol. 51: 119—133. PMID 12602896.
- ^ Huber, D.P.W., Philippe, R.N., Godard, K.-A., Sturrock, R.N. and Bohlmann, J. (2005). „Characterization of four terpene synthase cDNAs from methyl jasmonate-induced Douglas-fir, Pseudotsuga menziesii”. Phytochemistry. 66: 1427—1439. PMID 15921711.
- ^ Landmann, C., Fink, B., Festner, M., Dregus, M., Engel, K.H. and Schwab, W. (2007). „Cloning and functional characterization of three terpene synthases from lavender (Lavandula angustifolia)”. Arch. Biochem. Biophys. 465: 417—429. PMID 17662687.
Literatura уреди
- Nicholas C. Price; Lewis Stevens (1999). Fundamentals of Enzymology: The Cell and Molecular Biology of Catalytic Proteins (Third изд.). USA: Oxford University Press. ISBN 019850229X.
- Eric J. Toone (2006). Advances in Enzymology and Related Areas of Molecular Biology, Protein Evolution (Volume 75 изд.). Wiley-Interscience. ISBN 0471205036.
- Branden C; Tooze J. Introduction to Protein Structure. New York, NY: Garland Publishing. ISBN 0-8153-2305-0.
- Irwin H. Segel. Enzyme Kinetics: Behavior and Analysis of Rapid Equilibrium and Steady-State Enzyme Systems (Book 44 изд.). Wiley Classics Library. ISBN 0471303097.
Spoljašnje veze уреди
- Terpinolene+synthase на US National Library of Medicine Medical Subject Headings (MeSH)
