(4S)-limonenska sintaza
(4S)-limonenska sintaza (EC 4.2.3.16, (-)-(4S)-limonenska sintaza, 4S-(-)-limonenska sintaza, geranildifosfat difosfatna lijaza (formira limonen), geranildifosfat difosfatna lijaza (ciklizacija, formira (4S)-limonen), geranil-difosfat difosfat-lijaza (ciklizacija, formira (-)-(4S)-limonen)) je enzim sa sistematskim imenom geranil-difosfat difosfat-lijaza (ciklizacija, formira (S)-limonen).[1][2][3] Ovaj enzim katalizuje sledeću hemijsku reakciju
| (4S)-limonenska sintaza | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifikatori | |||||||||
| EC broj | 4.2.3.16 | ||||||||
| CAS broj | 110639-20-8 | ||||||||
| Baze podataka | |||||||||
| IntEnz | IntEnz pregled | ||||||||
| BRENDA | BRENDA pristup | ||||||||
| ExPASy | NiceZyme pregled | ||||||||
| KEGG | KEGG pristup | ||||||||
| MetaCyc | metabolički put | ||||||||
| PRIAM | profil | ||||||||
| Strukture PBP | RCSB PDB PDBe PDBj PDBsum | ||||||||
| |||||||||
- geranil difosfat (S)-limonen + difosfat
Rekombinantni enzim iz Abies grandis deluje u prisustvu jona Mn2+ i K+.
Reference уреди
- ^ Bohlmann, J., Steele, C.L. and Croteau, R. (1997). „Monoterpene synthases from grand fir (Abies grandis). cDNA isolation, characterization, and functional expression of myrcene synthase, (-)-(4S)-limonene synthase, and (-)-(1S,5S)-pinene synthase”. J. Biol. Chem. 272: 21784—21792. PMID 9268308.
- ^ Collby, S.M., Alonso, W.R., Katahira, E.J., McGarvey, D.J. and Croteau, R. (1993). „4S-Limonene synthase from the oil glands of spearmint (Mentha spicata). cDNA isolation, characterization, and bacterial expression of the catalytically active monoterpene cyclase”. J. Biol. Chem. 268: 23016—23024. PMID 8226816.
- ^ Yuba, A., Yazaki, K., Tabata, M., Honda, G. and Croteau, R. (1996). „cDNA cloning, characterization, and functional expression of 4S-(-)-limonene synthase from Perilla frutescens”. Arch. Biochem. Biophys. 332: 280—287. PMID 8806736.
Literatura уреди
- Nicholas C. Price; Lewis Stevens (1999). Fundamentals of Enzymology: The Cell and Molecular Biology of Catalytic Proteins (Third изд.). USA: Oxford University Press. ISBN 019850229X.
- Eric J. Toone (2006). Advances in Enzymology and Related Areas of Molecular Biology, Protein Evolution (Volume 75 изд.). Wiley-Interscience. ISBN 0471205036.
- Branden C; Tooze J. Introduction to Protein Structure. New York, NY: Garland Publishing. ISBN 0-8153-2305-0.
- Irwin H. Segel. Enzyme Kinetics: Behavior and Analysis of Rapid Equilibrium and Steady-State Enzyme Systems (Book 44 изд.). Wiley Classics Library. ISBN 0471303097.
- William P. Jencks (1987). Catalysis in Chemistry and Enzymology. Dover Publications. ISBN 0486654605.
Spoljašnje veze уреди
- (4S)-limonene+synthase на US National Library of Medicine Medical Subject Headings (MeSH)
