Oktadekanalna dekarbonilaza
Oktadekanalna dekarbonilaza (EC 4.1.99.5, dekarbonilaza, aldehidna dekarbonilaza) je enzim sa sistematskim imenom octadekanal alkan-lijaza.[1][2][3] Ovaj enzim katalizuje sledeću hemijsku reakciju
| Oktadekanalna dekarbonilaza | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifikatori | |||||||||
| EC broj | 4.1.99.5 | ||||||||
| CAS broj | 94185-90-7 | ||||||||
| Baze podataka | |||||||||
| IntEnz | IntEnz pregled | ||||||||
| BRENDA | BRENDA pristup | ||||||||
| ExPASy | NiceZyme pregled | ||||||||
| KEGG | KEGG pristup | ||||||||
| MetaCyc | metabolički put | ||||||||
| PRIAM | profil | ||||||||
| Strukture PBP | RCSB PDB PDBe PDBj PDBsum | ||||||||
| |||||||||
- oktadekanal + O2 + 2 NADPH + 2 H+ heptadekan + format + H2O + 2 NADP+
Ovaj enzim sadrži centar sa dva atoma gvožđa.
Reference
уреди- ^ Cheesbrough, T.M. & , K olattukudy, P.E. (1984). „Alkane biosynthesis by decarbonylation of aldehydes catalyzed by a particulate preparation from Pisum sativum”. Proc. Natl. Acad. Sci. USA. 81: 6613—6617. PMID 6593720.
- ^ Schirmer, A., Rude, M.A., Li, X., Popova, E. and del Cardayre, S.B. (2010). „Microbial biosynthesis of alkanes”. Science. 329: 559—562. PMID 20671186.
- ^ Warui, D.M., Li, N., Nørgaard, H., Krebs, C., Bollinger, J.M. and Booker, S.J. (2011). „Detection of formate, rather than carbon monoxide, as the stoichiometric coproduct in conversion of fatty aldehydes to alkanes by a cyanobacterial aldehyde decarbonylase”. J. Am. Chem. Soc. 133: 3316—3319. PMID 21341652.
Literatura
уреди- Nicholas C. Price; Lewis Stevens (1999). Fundamentals of Enzymology: The Cell and Molecular Biology of Catalytic Proteins (Third изд.). USA: Oxford University Press. ISBN 019850229X.
- Eric J. Toone (2006). Advances in Enzymology and Related Areas of Molecular Biology, Protein Evolution (Volume 75 изд.). Wiley-Interscience. ISBN 0471205036.
- Branden C; Tooze J. Introduction to Protein Structure. New York, NY: Garland Publishing. ISBN 0-8153-2305-0.
- Irwin H. Segel. Enzyme Kinetics: Behavior and Analysis of Rapid Equilibrium and Steady-State Enzyme Systems (Book 44 изд.). Wiley Classics Library. ISBN 0471303097.
- William P. Jencks (1987). Catalysis in Chemistry and Enzymology. Dover Publications. ISBN 0486654605.
Spoljašnje veze
уреди- Octadecanal+decarbonylase на US National Library of Medicine Medical Subject Headings (MeSH)